How long of burn time on high fire on both burners? When I had my furnace, I would burn very long on high fire, and the clinker would make like a crown around the inside of the burn pot and start blocking off the air supply. Then the corn would be half burned and look like black Styrofoam. I had gotten a second timer for the furnace to give the burn pot a short while to cool off and the clinker would separate from the burn pot as it cooled. It replaced the relay, just plugged in. Since this is happening in your boiler, I would try a mix of some pellets with the corn. You get a much nicer complete burn, and the ash from the pellets help make the clinker a bit softer and seems to burn much more complete. Good luck. Rob